Rhodium and triphenylphosphine catalyst system has been used for the hydroformylation of soybean, safflower and linseed oils and their methyl esters. Polymer supported triphenylphosphine has been reported to efficiently catalyze the γ-addition of pronucleophiles to alkynoate. Triphenylphosphine reacts with hydrated ruthenium trichloride in methanol to afford [RuCl2(PPh3)4], [RuCl2(PPh3)3] and [RuCl3(PPh3)2CH3OH]. It participates in the Heck reaction of 4-bromoanisole and ethyl acrylate in ionic liquids.
Synonyms: Phosphorustriphenyl
Molecular Formula: C18H15P
Molecular Weight: 262.29
Linear Structural Formula: (C6H5)3P
MDL Number: MFCD00003043
Purity: 99%
Melting Point: 79-81 C (lit.)
Application: Triphenylphosphine was used in the synthesis of mono-6-amino-deoxy-6-cyclodextrin. It was also employed as catalyst during the synthesis of C-aryl furanosides.
Legal Information: ReagentPlus is a registered trademark of Sigma-Aldrich Co. LLC
Assay: 99%
BP: 377°C(lit.)
Grade: ReagentPlus®
MP: 79-81°C(lit.)
Vapor Density: 9 (vs air)
Vapor Pressure: 5 mmHg ( 20°C)