Synonyms: tBuBrettPhos OAC precatalyst TES
Molecular Formula: C43H66BrO4PPdSi
Molecular Weight: 892.37
Linear Structural Formula: C43H66BrO4PPdSi
Melting Point: >300 C
Application: tBuBrettPhos Pd G6 TES is a G6 Buchwald precatalyst. The G6 precatalysts are air-stable, palladium-based oxidative addition complexes (OACs) that offer an alternative to the previously developed classes of palladacycle precatalysts. Unlike previous generations, the bulkiest biarylphosphine ligand precatalysts are readily prepared. These precatalysts have been shown to be effective for many reactions, including C-N, C-O, and C-F cross couplings.
Other Notes: Oxidative Addition Complexes as Precatalysts for Cross-Coupling Reactions Requiring Extremely Bulky Biarylphosphine LigandsMonophosphine Ligands Promote Pd-Catalyzed C-S Cross-Coupling Reactions at Room Temperature with Soluble Base