Synonyms: Davies dirhodium catalyst; Dirhodium tetrakis((S,R)-1-(4-bromophenyl)-2,2-diphenylcyclopropanecarboxylate); Dirhodium tetrakis[(R)-1-(4-bromophenyl)-2,2- diphenylcyclopropane carboxylate]; Tetrakis[(R)-(-)-[(1R)-1-(4-bromophenyl)-2,2-diphenylcyclopropanecarboxylato]dirhodium(II); Tetrakis[(R)-1-(4-bromophenyl)-2,2- diphenylcyclopropane carboxylato]dirhodium(II)
Molecular Formula: C88H64Br4O8Rh2
Molecular Weight: 1774.87
Linear Structural Formula: C88H64Br4O8Rh2
Melting Point: >300 C
Application: Rh catalyst developed by the Davies lab used for enantioselective cyclopropanations and C-H funcionalization under low catalyst loadings.
Other Notes: D2-Symmetric Dirhodium Catalyst Derived from a 1,2,2-Triarylcyclopropanecarboxylate Ligand: Design, Synthesis and ApplicationEnantioselective Synthesis of 2-Arylbicyclo[1.1.0]butane CarboxylatesSite-selective and stereoselective functionalization of non-activated tertiary C-H bonds