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"Triethyl phosphonoacetate, purum, Greater Than or Equal to 97.0% (GC)"

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Synonym(s): (Diethoxyphosphinyl)acetic acid ethyl ester; Diethyl ethoxycarbonylmethylphosphonate; NSC 13898; NSC 16128; Triethyl carboxymethylphosphonate

Formula: (C2H5O)2P(O)CH2CO2C2H5

Formula Weight: 224.19

CAS No.: 867-13-0

UN Number: UN3082

Purity: ≥97.0% (GC)

Density: 1.13g/mLat 25°C(lit.)

Application: Reactant involved in:
• Horner-Wadsworth-Emmons reactions1,
• Intramolecular Heck-type cyclization and isomerizations
• Tsuji-Trost type reactions
• Intramolecular aryne-ene reactions
• Synthesis of aldehydes

Other Notes: A Horner-Wittig reagent, review7,8; Improved procedure for the C2 homologation of esters to α,β-unsaturated esters9; Synthesis of α-(hydroxymethyl)acrylate10

Beilstein Registry Number: 1343714

EC No.: 212-757-6

Boiling Point: 142-145°C/9mmHg(lit.)

Refractive Index: n20/D 1.431(lit.); n20/D 1.432

Empirical Formula (Hill Notation): C5H7N3

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Product Detail
Thomas No.
C981V80
Mfr. No.
79525-100ML
Description
Triethyl phosphonoacetate, purum, Greater Than or Equal to 97.0% (GC), 100 mL
Packaging Size
100 mL
list price/quantitytotal
$0.00
$0.00 (0 Items)
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