CAS Number: 32248-43-4
Formula: I2Sm
Formula Weight: 404.17
Linear Formula: SmI2
MDL No.: MFCD00058873
Density: 0.922 g/mL at 25 C
Storage: 2-8C
UNSPSC Code: 12352000
Application: An effective single-electron reducing agent for the promotion of ketone-olefin and pinacol coupling reactions under mild conditions. Often both intramolecular and intermolecular couplings proceed in a highly stereoselective fashion. Starting material for the synthesis of new heteroleptic samarium aryloxide/cyclopentadienide complexes.
Application: A promoter of reactions involving samarium ketyl aryl cyclizations.
RIDADR: UN 2056 3 / PGII
WGK Germany: 3
Flash Point(F): -2.2 F
Flash Point(C): -19 C
R Codes: 11-19-36/37-40
S Codes: 16-26-36/37
IOD Codes: F,Xn
Symbol: GHS02, GHS07, GHS08
Signal Word: Danger
Hazard Statements: H225-H319-H335-H351-H373
Precautionary statements: P210-P260-P280-P305 + P351 + P338-P370 + P378-P403 + P235