Palladium(II) chloride (PdCl2) reacts with unsubstituted or alkyl-substituted cyclic ketones in the CO atmosphere to afford acyclic diesters and acyclic chloro-substituted monoesters. PdCl2 reacts with N,N-dimethylallylamine in methanol to afford di-μ-chloro-bis(2-methoxy-3-N,N-dimethylaminopropyl)dipalladium(II). Palladium dichloride, acetate and acetylacetonate in the [bmim][BF4] or [bmim][PF6] (where[bmim]+ = 1-butyl-3-methylimidazolium cation) ionic liquids have been employed for the hydrodimerization of butadiene to form octa-2,7-dien-1-ol.
Molecular Formula: Cl2Pd
Molecular Weight: 177.33
Linear Structural Formula: Cl2Pd
MDL Number: MFCD00003558
Purity: >=99.9%
Melting Point: 678-680 C (lit.)
Density: 4 g/mL at 25 C (lit.)
Application: Palladium(II) chloride (PdCl2) was used in the following studies:
•As catalyst for the carbonylation of organic tellurides by reaction with carbon monoxide.
•As a catalyst along with Cu(II) for the deamination of phenethylamines to phenyl substituted pyrroles.
•Together with PEG 300, promoted efficient Suzuki-coupling of aryl chlorides with aryl boronic acids.
EC No.: 231-596-2
Melting Point: 678-680°C(lit.)
Empirical Formula (Hill Notation): C12H15NO2 · HCl