Synonyms: TMIS; Trimethyliodosilane
CAS Number: 16029-98-4
Formula: C3H9ISi
Formula Weight: 200.09
Linear Formula: (CH3)3SiI
MDL No.: MFCD00001028
Purity: 0.97
Boiling Point: 106 C(lit.)
Density: 1.406 g/mL at 25 C(lit.)
Refractive Index: n20/D 1.471(lit.)
Storage: -20C
Beilstein Registry Number: 1731136
EC Number: 240-171-0
UNSPSC Code: 12352000
Application: Efficient reagent for cleaving ethers, esters, carbamates, ketals, and lactones.
Application: Reagent was recently reported to convert allyl- and benzylphosphotriesters to the corresponding iodides.
Application: For the introduction of the TMS group, e.g., TMS enol ethers. Key reagent for the selective deprotection of an N-Cbz group in the presence of a trimethyltin moiety.
RIDADR: UN 2924 8(3) / PGII
WGK Germany: 3
Flash Point(F): -23.8 F
Flash Point(C): -31 C
R Codes: 12737
S Codes: 16-26-36/37/39-43-45
IOD Codes: F,C
Symbol: GHS02, GHS05
Signal Word: Danger
Hazard Statements: H225-H314
Precautionary statements: P210-P280-P305 + P351 + P338-P310