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MilliporeSigma

Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct,

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Synonyms: Bis(trimethylaluminum)-DABCO(R) adduct; DABAL-Me3; DABAL-trimethylaluminum; Triethylenediaminine bis(trimethylaluminum)

CAS Number: 137203-34-0

Formula: C12H30Al2N2

Formula Weight: 256.34

Linear Formula: (CH3)3Al · C6H12N2 · Al(CH3)3

MDL No.: MFCD09265160

Melting Point: >250 C

UNSPSC Code: 12352103

General description: Product is air and moisture sensitive. Handle and store under a dry, inert atmosphere.

Application: DABAL-Me3: An Air Stable "Methyl Anion"

Application: A more stable alternative to trimethylaluminum for use in numerous reactions including methylations of aldehydes and imines, methylations of aryl and vinyl halides, conjugate addition to enones, and amide bond formation.

RIDADR: UN 3395 4.3 / PGI

WGK Germany: 3

R Codes: 14-15-22-36/37/38

S Codes: 16-26-43

IOD Codes: F,Xn

Symbol: GHS02, GHS07

Signal Word: Danger

Hazard Statements: H260-H302-H315-H319-H335

Precautionary statements: P223-P231 + P232-P261-P305 + P351 + P338-P370 + P378-P422

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Product Detail
Thomas No.
C981J90
Mfr. No.
682101-5G
Description
Bis(trimethylaluminum)-1,4-diazabicyclo[2.2.2]octane adduct, , 5 g
CAS Number
137203-34-0
Packaging Size
5 g
Packaging Type
Bottle, Glass
list price/quantitytotal
$0.00
$0.00 (0 Items)
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