Synonyms: Di-Ad-BrettPhos-G3-Palladacycle; [2-(Di-1-adamantylphosphino)-2',4',6'-triisopropyl-3,6-dimethoxybiphenyl][2-(2'-amino-1,1'-biphenyl)]palladium(II) methanesulfonate
Molecular Formula: C56H74NO5PPdS
Molecular Weight: 1010.65
Linear Structural Formula: C56H74NO5PPdS
MDL Number: MFCD27952546
Melting Point: 251-253 C
Application: Buchwald 3rd Generation Pd Precatalyst adorned by the bulk di-adamntyl BrettPhos ligand. This complex has been used in the monoarylation of ammonia, displaying apptitude for otherwise difficult 5-member heterocyclic substrates.Mild and Highly Selective Palladium-Catalyzed Monoarylation of Ammonia Enabled by the Use of Bulky Biarylphosphine Ligands and Palladacycle Precatalysts