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MilliporeSigma

2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution, 1.0 M in THF/toluene

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2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution, 1.0 M in THF/toluene

Synonyms: TMPMgCl·LiCl

CAS Number: 898838-07-8

Formula: C9H18Cl2LiMgN

Formula Weight: 242.4

Linear Formula: C9H18Cl2LiMgN

MDL No.: MFCD12546030

Density: 0.96 g/mL at 25 C

Storage: 2-8C

UNSPSC Code: 12352103

Application: 2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex is a non-nucleophilic Knochel-Hauser base mainly used for the magnesiation of functionalized arenes and heteroarenes to prepare the corresponding Grignard reagents. It can also be used as a base in the synthesis of Π-conjugated polymers via catalyst-transfer polycondensation.

Application: Selective Deprotonations using Knochel-Hauser-Base

RIDADR: UN 3399A 4.3(3) / PGI

WGK Germany: 3

Flash Point(F): 5 F

Flash Point(C): -15 C

R Codes: 63-11-14-19-34-37-40

S Codes: 16-26-36/37/39-45

IOD Codes: F,C

Symbol: GHS02, GHS05, GHS07, GHS08

Signal Word: Danger

Hazard Statements: H225-H302-H314-H335-H351-H361d

Precautionary statements: P210-P260-P280-P305 + P351 + P338-P370 + P378-P403 + P235

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Product Detail
Thomas No.
C981N04
Mfr. No.
703540-100ML
Description
2,2,6,6-Tetramethylpiperidinylmagnesium chloride lithium chloride complex solution, 1.0M in THF/toluene, 100 mL
CAS Number
898838-07-8
Packaging Size
100 mL
Packaging Type
Sure/Seal™
list price/quantitytotal
$0.00
$0.00 (0 Items)
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