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MilliporeSigma

2,2-Dimethyl-1,3-dioxane-4,6-dione

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2,2-Dimethyl-1,3-dioxane-4,6-dione

Synonym: Malonic acid cyclic isopropylidene ester, Meldrum’s acid, cycl-Isopropylidene malonate

CAS Number: 2033-24-1

Empirical Formula (Hill Notation): C6H8O4

Molecular Weight: 144.13

Packaging: 10, 25, 100 g in glass bottle

Application:
Benzyl substituted Meldrum's acids, available via aldol condensation and reduction with triethylammonium formate,1 were used to form indanones upon hydrolysis, loss of CO2, and Friedel-Crafts cyclization with chlorosulfonic acid.2 Knoevenagel condensations between aldehydes and Meldrum's acid are accelerated in ionic liquids.3

Used in an efficient synthesis of isofraxidin.

Assay: =90% (GC)

MP: 92-96 °C(lit.)

Storage temp.: 2-8°C

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Product Detail
Thomas No.
C986W38
Mfr. No.
210145-10G
Description
2,2-Dimethyl-1,3-dioxane-4,6-dione, 98%, 10g
list price/quantitytotal
$0.00
Thomas No.
C986W39
Mfr. No.
210145-25G
Description
2,2-Dimethyl-1,3-dioxane-4,6-dione, 98%, 25g
list price/quantitytotal
$0.00
Thomas No.
C986W40
Mfr. No.
210145-100G
Description
2,2-Dimethyl-1,3-dioxane-4,6-dione, 98%, 100g
list price/quantitytotal
$0.00
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