Synonyms: Bis(cyclooctadiene)nickel; Ni(COD)2
CAS Number: 1295-35-8
Formula: C16H24Ni
Formula Weight: 275.06
Linear Formula: C16H24Ni
MDL No.: MFCD00058902
Melting Point: 60 C (dec.) (lit.)
Storage: -20C
EC Number: 215-072-0
UNSPSC Code: 12352300
Application: Used to catalyze the addition of allyl phenyl sulfide to alkynes leading to 1,4-dienes. The reaction with terminal acetylenes proceeds in high yield and high selectivity. A variety of functional groups are tolerated.
Application: Catalyst for the cycloaddition of 1,3-dienes.
Application: Reactant for:. Oxidative addition reactionsCatalyst for:. Asymmetric α-arylation and heteroarylation of ketones with chloroarenes. Cross-coupling reactions. Regioselective and stereoselective carboxylation/cyclization of allenyl aldehydes under a carbon dioxide atmosphere. Methyl carboxylation of homopropargylic alcohols. Stereoselective borylative ketone-diene coupling. Cycloaddition of benzamides with internal alkynes
RTECS: QR6135000
RIDADR: UN1325 - class 4.1 - PG 2 - Flammable solids, organic, n.o.s., HI: all
WGK Germany: 3
R Codes: 14916
S Codes: 36/37
IOD Codes: F,Xn
Symbol: GHS02, GHS08
Signal Word: Danger
Hazard Statements: H228-H334-H351
Precautionary statements: P210-P261-P280-P304 + P340-P308 + P313-P370 + P378