Synonyms: Aluminumtriethanide
CAS Number: 97-93-8
Formula: C6H15Al
Formula Weight: 114.16
Linear Formula: Al(C2H5)3
MDL No.: MFCD00009015
Density: 0.692 g/mL at 25 C
Beilstein Registry Number: 3587229
UNSPSC Code: 12352103
Application: Triethylaluminum solution can be used: . As a reagent in Alumino-Mannich reaction, where it reacts with iminium ion substrates for which the corresponding Petasis borono-Mannich reaction is unsuccessful.. In the synthesis of macrocyclic binuclear aluminum complexes with efficient activities toward ring-opening polymerization of ε-caprolactone.. To promote Claisen rearrangement of allyl vinyl ether derivatives along with the transfer of ethyl group to aldehydic carbon.. As a reagent for copper-catalyzed asymmetric conjugate addition of alkenyl- and alkylalanes to α,β-unsaturated lactams.. As a precursor to synthesize diethylaluminium cyanide, which is used as hydrocyanating reagent.
RIDADR: UN3394 - class 4.2 - PG 1 - EHS - Organometallic substance, liquid, pyrophoric, water-reactive, HI: all (not BR)
WGK Germany: 2
Flash Point(F): -.4 F
Flash Point(C): -18 C
R Codes: 11-14-17-34-48/20-51/53-62-65-67
S Codes: 16-26-36/37/39-45-61-62
IOD Codes: F,C,N
Symbol: GHS02, GHS05, GHS07, GHS08, GHS09
Signal Word: Danger
Hazard Statements: H225-H250-H260-H304-H314-H336-H361f-H373-H411
Precautionary statements: P210-P231 + P232-P280-P305 + P351 + P338-P370 + P378-P422