Synonyms: TBAB
CAS Number: 64-20-0
Formula: C4H12BrN
Formula Weight: 154.05
Linear Formula: (CH3)4N(Br)
MDL No.: MFCD00011626
Purity: 0.98
Melting Point: >300 C (lit.)
Beilstein Registry Number: 3620955
EC Number: 200-581-2
UNSPSC Code: 12352100
General description: Tetrabutylammonium bromide is a quaternary ammonium compound that is widely used as a phase transfer catalyst. Absolute viscosities of its aqueous solutions have been measured at various temperatures (20,25 and 30C). Various physical properties (activity coefficient up to saturation, conductance, density and solubility in water) of TMABr have been evaluated.
General description: Tetramethylammonium bromide (TMABr) is a quaternary ammonium salt. Absolute viscosities of its aqueous solutions have been measured at various temperatures (20,25 and 30C). Various physical properties (activity coefficient up to saturation, conductance, density and solubility in water) of TMABr have been evaluated. Its impact on the first order rate constant values for the base hydrolysis of the following Fe(II) chelates has been investigated:4 . bis(naphthylidene alanate) (nali) . bis(naphthylidene phenylalanate) (nphali). bis(naphthylidene aspartate) (nasi) . (naphthylidene histidinate) (nhi) . bis(naphthylidenearginate) (nari)
Application: Tetrabutylammonium bromide may be used in the molten state in the following processes:. Synthesis of (2S)-5-(3-phenyl-2-phthalimidylpropanoylamino)isophthalic acid.. Synthesis of alkyl-substituted pyrroles in the absence of catalyst and organic solvent.. Synthesis of dithioacetals from acetals by transthioacetalisation in a solvent free environment.. Synthesis of polyamides (PAs) by the polymerization of terephthalic acid and diisocyanates.. Catalyze the addition of thiols to conjugated alkenes.. Dehydrochlorination of poly(vinyl chloride).
Application: Tetramethylammonium bromide may be used as a template in the synthesis of small colloidal zeolite Y nanocrystals.
RTECS: BS7600000
RIDADR: UN 2811 6.1 / PGII
WGK Germany: 3
R Codes: 25-36/37/38
S Codes: 26-28-36-45
IOD Codes: T
Symbol: GHS06
Signal Word: Danger
Hazard Statements: H300
Precautionary statements: Missing Phrase - N15.00950417