Synonyms: (eta5-Cyclopentadienyl)(eta6-naphthalene)ruthenium(1+) trifluoromethanesulfonate
Molecular Formula: C16H13F3O3RuS
Molecular Weight: 443.4
Linear Structural Formula: C16H13F3O3RuS
Purity: >=95%
Melting Point: 112-116 C
Storage: 2-8C
Application: Stable precursor for synthesis and ruthenium catalysis. It was also used by the Ritter lab to synthesize an Fmoc-protected ruthenium tyrosine for subsequent incorporation of the [18F]fluoride radiolabel into polypeptides.
Other Notes: Site-Specific Deoxyfluorination of Small Peptides with [18F]FluorideComparison of the Catalytic Activity of [(5-C5H5)Ru(2,2′-bipyridine)(L)]OTf versus [(5-C5H5)Ru(6,6′-diamino-2,2′-bipyridine)(L)]OTf (L = labile ligand) in the Hydrogenation of Cyclohexanone. Evidence for the Presence of a Metal–Ligand Bifunctional Mechanism under Acidic Conditions Arene Exchange in the Ruthenium-Naphthalene Complex [CpRu(C10H8)]+