Synonyms: Iridium(III) bis[2-(2,4-difluorophenyl)-5-methylpyridine-N,C20]-4,40-di-tert-butyl-2,20-bipyridine hexafluorophosphate
Molecular Formula: C42H40F10IrN4P
Molecular Weight: 1013.97
Linear Structural Formula: C42H40F10IrN4P
Application: [Ir(dF(Me)ppy)2(dtbbpy)]PF6 is a photocatalyst readily facilitates hydroamination of olefins as well as the decarboxylative arylation and vinylation of carboxylic acids via metallaphotoredox catalysis.
Other Notes: Catalytic intermolecular hydroaminations of unactivated olefins with secondary alkyl aminesMerging photoredox and nickel catalysis: Decarboxylative cross-coupling of carboxylic acids with vinyl halidesEnhanced luminescent iridium(III) complexes bearing aryltriazole cyclometallated ligandsSite-Selective and Stereoselective C-H Alkylations of Carbohydrates via Combined Diarylborinic Acid and Photoredox Catalysis