Synonyms: 3-Chloro-1-propyne
CAS Number: 624-65-7
Formula: C3H3Cl
Formula Weight: 74.51
Linear Formula: HC///CCH2Cl
MDL No.: MFCD00000980
Density: 0.963 g/mL at 25 C
Refractive Index: n20/D 1.456
Storage: 2-8C
Beilstein Registry Number: 506005
UNSPSC Code: 12352100
General description: Product is the 70wt.% solution of propargyl chloride in toluene. Propargyl chloride is a propargyl halide. Its trimethylsilylation reaction has been reported. Liquid-phase Raman spectra, and vapor-phase and solution-phase infrared spectra of propargyl chloride has been studied at 100-3400cm-1 and 300-3800cm-1, respectively. It participates in the addition reaction with acyclic 1,3-dienes (at -78C) in the presence of zinc chloride.
Application: Propargyl chloride solution may be used for the enantioselective synthesis of enantiomerically enriched homopropargyl alcohols.
Application: Propargyl chloride may be used as propargylating agent in the preparation of arabinogalactan propargyl ethers with degree of substitution up to 1.8. It may be used for the in situ preparation of propargyltrichlorosilane and allenyltrichlorosilane, required for the synthesis of optically active allenic and homopropargylic alcohols.
RIDADR: UN 3286 8(6.1)(3) / PGII
WGK Germany: 3
Flash Point(F): 66.2 F
Flash Point(C): 19 C
R Codes: 63-11-23/24/25-34-48/20-65
S Codes: 16-26-36/37/39-45-62
IOD Codes: F,T
Symbol: GHS02, GHS05, GHS06, GHS08
Signal Word: Danger
Hazard Statements: H225-H301 + H311 + H331-H304-H314-H336-H361d-H373
Precautionary statements: P210-P261-P280-P301 + P310-P305 + P351 + P338-P310