Synonyms: LDA
CAS Number: 4111-54-0
Formula: C6H14LiN
Formula Weight: 107.12
Linear Formula: [(CH3)2CH]2NLi
MDL No.: MFCD00064449
Density: 0.812 g/mL at 25 C
Storage: 2-8C
Beilstein Registry Number: 3655042
UNSPSC Code: 12352000
Application: Titanium-ate enolates prepared from ketones by Ti(OiPr)4 and LDA underwent efficient radical trifluoromethylation providing trifluoromethyl ketones in good yield. Used in directed ortho-lithiation of arylsulfonyloxazolidinones to prepare N-substituted saccharin analogs.
RIDADR: UN3399 - class 4.3 - PG 2 - EHS - Organometallic substance, liquid, water-reactive, flammable, HI: all (not BR)
WGK Germany: 3
Flash Point(F): 35.6 F
Flash Point(C): 2 C
R Codes: 63-11-14-17-19-34-37-40-48/20-51/53-62-65-67
S Codes: 16-26-36/37/39-45-61-62
IOD Codes: F,C,N
Symbol: GHS02, GHS05, GHS07, GHS08, GHS09
Signal Word: Danger
Hazard Statements: H225-H304-H314-H335-H336-H351-H373-H411
Precautionary statements: P210-P260-P273-P280-P301 + P310-P301 + P330 + P331-P303 + P361 + P353-P304 + P340 + P310-P305 + P351 + P338 + P310-P370 + P378-P391