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MilliporeSigma

(-)-DIP-Chloride(TM),

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Synonyms: (-)-B-Chlorodiisopinocampheylborane; (-)-Ipc2BCl

CAS Number: 85116-37-6

Formula: C20H34BCl

Formula Weight: 320.75

Linear Formula: C20H34BCl

MDL No.: MFCD00074807

Melting Point: 52-56 C (lit.)

Beilstein Registry Number: 5937756

UNSPSC Code: 12352000

Application: Reagent used for an enantioselective reduction of (chloroacetyl) benzofurans to chlorohydrins which serve as intermediates for the corresponding epoxides and aminoalcohols. For a short paper on the preparation of DIP halides and their use in stereoselective reductions see Chem. Commun. 1053 (1994).

Application: Both (+)- and (-)-DIP-chloride are used for asymmetric reduction of prochiral ketones and for the preparation of β-amino alcohols.

RIDADR: UN 3261 8 / PGII

WGK Germany: 3

Flash Point(F): 230 F

Flash Point(C): 110 C

R Codes: 34

S Codes: 26-36/37/39-45

IOD Codes: C

Symbol: GHS05

Signal Word: Danger

Hazard Statements: H314

Precautionary statements: P280-P305 + P351 + P338-P310

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Product Detail
Thomas No.
C951J07
Mfr. No.
317020-100G
Description
(-)-DIP-Chloride™, 100G

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